Thermodynamics

Mole

The mole $N$ is a measurement for the amount of substance of a system.

Unit

$$ [N] = mol $$

Avogadro number

The Avogadro number $N_A$ is the number of particles in 1 mole of 12$g$ of $\ce{^12C}$.

$$N_A = 6.022 \cdot 10^{23}$$

Pressure

When a force $\overrightarrow{F}$ with the perpendicuar component $F_{\bot}$ is applied on a surface $A$, we can define the pressure $P$ exerted on the surface $A$ as:

Formula

$$ P = \frac{F_{\bot}}{A} $$

Unit

$$ [P] = \frac{N}{m^2} = Pa $$ $$ Pa,\ Pascal $$

Remark

Pressure is a scalar quantity.

Pressure units

Pressure has a lot of weird units that have historical or practical significance. See: Exotische Umwandlungen.

Critical Temperature

The critical temperature $T_c$ is the temperature where above the critical temperature the system cannot liquify anymore, no matter how much the pressure is increased.

Triple point of Water

The triple point for water is the temperature and pressure where the 3 phases of water, vapour, liquid, gas, coexists at the same time.
This occurs for $T=0.01^{\circ}C$ and $P=611Pa$

triple point of water

Gas and vapour

The terms gas and vapour cannot be used interchangeably:

Gas universal constant

$$ R=8.314 \frac{J}{mol \cdot K} $$

Perfect gas

Perfect gas has the following properties:

Formula

$$ PV = nRT $$

Kinetic Theory of Gases